/*
<Names>
<Name>
<FirstName>John</FirstName>
<LastName>Smith</LastName>
</Name>
<Name>
<FirstName>James</FirstName>
<LastName>White</LastName>
</Name>
</Names>
*/
XmlDocument xml = new XmlDocument();
xml.LoadXml(myXmlString); // suppose that myXmlString contains "<Names>...</Names>"
XmlNodeList xnList = xml.SelectNodes("/Names/Name");
foreach (XmlNode xn in xnList)
{
string firstName = xn["FirstName"].InnerText;
string lastName = xn["LastName"].InnerText;
Console.WriteLine("Name: {0} {1}", firstName, lastName);
}